Construction of quantitative molecular isotherms from FTIR analysis of dinitrogen (N2) adsorption on a microporous NaY zeolite.

نویسنده

  • Olivier Cairon
چکیده

We focus on the analysis of N(2) adsorption on NaY faujasite investigated by means of both the FTIR and volumetric measurements. We examine how these two approaches, when combined, can lead to a more advanced quantitative description featuring the understanding of gas adsorption both at the molecular and the macroscopic scales. For this task, we describe hereafter the method used and how we circumvented drawbacks encountered along the way. Finally we share new insight obtained by working step by step towards the construction of the first quantitative molecular isotherms of N(2) on a NaY zeolite.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Enhancement of CO2/CH4 Adsorptive Selectivity by Functionalized Nano Zeolite

In this work, we have modified a synthesized Y-type zeolite (Si/Al = 2.5), with three different amines to investigate of the influence of adsorbent’s surface modification on CO2 selectivity over CH4. The pristine and amine-functionalized NaY zeolites were characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), Fourier transform infrared (FT-IR), and N2 adsorption. The resu...

متن کامل

Synthesis and characterization of composite molecular sieves comprising zeolite Beta with MCM-41 structures

Zeolite Beta/MCM-41 composites have been prepared with various crystallinities of zeolite Beta through a twostep crystallization process involving the combination of low crystallinity zeolite Beta synthesis gel with cetyltrimethylammonium bromide surfactant solution. The composites are characterized by XRD, SEM, Si and Al MAS NMR, N2 adsorption, NH3-TPD and catalytic cracking. The experimental ...

متن کامل

Template Assisted Method for Enhancing the Zeolite’s Ability to Capture Methionine

To investigate template effect on physicochemical properties of zeolite and enhance the molecular sieving properties, adsorption of methionine amino acid was studied by spectroscopic methods. Four zeolites such as methionine templated analcime, methionine templated zeolite P, N, N-dibenzyl N,N,N,N-tetramethylethylenediamine (DBTMED) templated analcime and free template analcime were synthesized...

متن کامل

Improving CO2 adsorption with new amine-functionalized Y-type zeolite

In this work, a new synthesized Y-type zeolite with an Si/Al molar ratio of 2.5 (NaY) was modified with amines, in order to probe the influence of the modification of the adsorbent’s surface on CO2 adsorption. The three selected amines were diethanolamine, tetraethylenepentamine, and 2- methylaminoethanol. The surface nature of NaY was changed after amine modification, which causes a...

متن کامل

A Molecular Simulation of Natural Gas Dehydration by 3A Zeolite Nanostructure

The adsorption and separation properties of 3A zeolite are investigated by using Grand Canonical Monte Carlo (GCMC) simulation. To obtain the adsorption isotherms of water, methyl mercaptan, and methane on 3A zeolite, COMPASS Force Filed is used. The adsorption isotherms of the pure components and the ternary mixtures of water, methyl mercaptan, and methane on 3A zeolites are calculated. The Si...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 14 35  شماره 

صفحات  -

تاریخ انتشار 2012